Vanadium(V) oxytrifluoride

Vanadium(V) oxytrifluoride is a chemical compound with the formula VOF3.[2] Characteristic of early metal fluorides, the structure is polymeric in the solid state.The solid adopts a layered structure but upon evaporation, the species becomes dimeric.In contrast VOCl3 and VOBr3 remain tetrahedral in all states, being volatile liquids at room temperature.[3] In organic synthesis, VOF3 is used for the oxidative coupling of phenols, for example in the syntheses of vancomycin and its analogues.
NFPA 704 four-colored diamond Health 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gas Flammability (red): no hazard code Instability (yellow): no hazard code Special hazards (white): no code
CAS NumberChemSpiderECHA InfoCardPubChemSMILESChemical formulaMolar massDensityMelting pointBoiling pointSolubility in waterGHS labellingPictogramsHazard statementsPrecautionary statementsNFPA 704standard statechemical compoundformulaorganic synthesisoxidative coupling of phenolstrifluoroacetic acidhexamethyldisiloxanevanadium dioxide fluorideVanadium compoundsV(CO)6V2(SO4)3V(C9H11)3V(S2)2VO(C5H7O2)2NH4VO3VO(ClO4)3VO(NO3)3Fluorine compoundsfluoridePd[PdF6]Te2F10Au2F10AuF5•F2LiAsF6NaAsF6NH4PF6LiSbF6NaSbF6(NH4)3[AlF6]Cs2AlF5Li3AlF6K3AlF6Na3AlF6SiIBrClFBaSiF6BaGeF6(NH4)2SiF6Na2[SiF6] K2[SiF6] Li2GeF6Li2SiF6ClO2F3CBr2F2CCl2F2C2Cl3F3C7H5F3C15F33NC6H11FCrF2O2(NH4)3CrF6(NH4)3GaF6(NH4)2GeF6(NH4)3FeF6(NH4)3InF6NH4NbF6(NH4)2SnF6NH4TaF6(NH4)3VF6(NH4)2ZrF6CsXeF7Li2SnF6Li2TiF6Li2ZrF6K2TiF6Rb2TiF6Na2TiF6Na2ZrF6K2NbF7K2TaF7K2ZrF6NH4HF2Chemical formulasinorganiccompound