Vanadyl perchlorate

Vanadyl perchlorate or vanadyl triperchlorate is a golden yellow coloured liquid or crystalline compound of vanadium, oxygen and perchlorate group.The substance consists of molecules covalently bound and is quite volatile; it ignites organic solvents on contact and explodes at temperatures above 80 °C.[1] Vanadyl perchlorate can be made by reacting vanadium pentoxide with dichlorine heptoxide at 5 °C.It is purified by distillation under a vacuum and recrystallisation at 21 °C.[5][6] Vanadic perchlorate, also known as vanadium(III) perchlorate solution in water, is a green-tinged blue colour, significantly different to most other V(III) solutions, which are complexed.
CAS NumberSMILESChemical formulaMolar massMelting pointBoiling pointOccupational safety and healthniobium perchloratevanadyl nitratestandard statevanadium pentoxidedichlorine heptoxidedichlorine hexoxidevanadium oxychlorideBibcodeperchlorateLiClO4B(ClO4)−4ROClO3NH4ClO4NOClO4NO2ClO4H3OClO4NaClO4Mg(ClO4)2Al(ClO4)−4Al(ClO4)3−6ClO−4ClOClO3Ca(ClO4)2Sc(ClO4)3Ti(ClO4)4Cr(ClO4)3Mn(ClO4)2Fe(ClO4)2Co(ClO4)2Ni(ClO4)2Cu(ClO4)2Zn(ClO4)2BrOClO3RbClO4Sr(ClO4)2Y(ClO4)3Zr(ClO4)4Nb(ClO4)5Rh(ClO4)3Pd(ClO4)2AgClO4In(ClO4)3CsClO4Ba(ClO4)2Au(ClO4)−4Pb(ClO4)2Pr(ClO4)3Nd(ClO4)3Sm(ClO4)3Gd(ClO4)3Tb(ClO4)3Vanadium compoundsV(CO)6V2(SO4)3V(C9H11)3V(S2)2VO(C5H7O2)2NH4VO3VO(NO3)3