Magnesium silicide

As-grown Mg2Si usually forms black crystals; they are semiconductors with n-type conductivity and have potential applications in thermoelectric generators.In the face-centered cubic lattice Si centers occupy the corners and face-centered positions of the unit cell and Mg centers occupy eight tetrahedral sites in the interior of the unit cell.[2] It can be produced by heating silicon dioxide, SiO2, found in sand, with excess magnesium.[5] Magnesium silicide is used to create aluminium alloys of the 6000 series, containing up to approximately 1.5% Mg2Si.Its as-grown crystal exhibit n-type conductivity, but it can be changed to p-type by doping with Ag, Ga, Sn and possibly Li (at high doping level).
The reaction of powdered sand with magnesium powder.
The reaction of magnesium silicide with 10% hydrochloric acid.
Preferred IUPAC nameCAS NumberChemSpiderECHA InfoCardEC NumberPubChemUN numberCompTox DashboardSMILESChemical formulaMolar massDensityMelting pointSolubility in waterCrystal structureAntifluoriteSpace groupLattice constantFormula unitsOccupational safety and healthsilaneGHS labellingPictogramsHazard statementsPrecautionary statementscationsCalcium silicidestandard stateinorganic compoundmagnesiumsiliconsemiconductorsthermoelectric generatorsface-centered cubicsilicon dioxidemagnesium oxidehydrochloric acidmagnesium chlorideSulfuric acidprotonolysisalkaline earth metalalkali metalsilicidesGuinier-Preston zonesnarrow-gap semiconductorCRC Handbook of Chemistry and PhysicsCRC PressBibcodeMagnesium compoundsMgC2O4MgC6H6O7C12H10Mg3O14C4H8MgN2O4MgC14H10O4Mg(ClO3)2Mg(ClO4)2Mg(HCO3)2Mg(HCO2)2MgHPO4Mg(H2PO4)2Mg(NO3)2Mg(OH)2Mg3(PO4)2MgU2O7Mg2Al3Mg5Ga2Mg2SiO4Mg2Si3O8Mg2(CrO4)2C24H46MgO4silicideSi4−Mn5Si3Fe5Si3more…