Aldaric acid
In this reaction it is the open-chain (polyhydroxyaldehyde) form of the sugar that reacts.Unlike their parent sugars, aldaric acids have the same functional group at both ends of their carbon chain; therefore, two different sugars can yield the same aldaric acid (this can be understood by looking at the Fischer projection of a sugar upside down—with normal aldoses, this is a different compound due to the aldehyde function at the top and the hydroxyl function at the bottom, but with aldaric acids, there is a carboxylic acid function on both ends, so upside down and right side up do not matter).A consequence of this is that some aldaric acids are meso forms with no optical activity despite their multiple chiral centers—this occurs if a sugar and its enantiomer oxidize to the same aldaric acid.An example is D-galactose—it has four chiral centers, but D-galactaric and L-galactaric acids, which have the opposite configuration at each chiral center and therefore would be expected to be enantiomers, are actually the same compound; therefore, galactaric acid is an achiral meso form with no optical activity.Again, this can be understood by taking the Fischer projection of either acid and looking at it upside down—the configuration is now switched at every carbon.